bahn makes a valiant attempt to correct misconceptions, but I believe still hangs on to one "unicorn tears" property of ethanol.
The autoignition temperature
reduces with increasing ethanol content. Most don't see this because of the extra cooling. However, if you push it too far with running lean, high boost, even without knock, you can blow impressive holes in things. Worthwhile having an EGT probe and aiming for a little lower than gasoline perhaps.
View attachment 13887
https://www.researchgate.net/public...of_Ethanol_and_E85_in_a_Spark_Ignition_Engine source of the above but only abstract available without paywall. E10 97 RON better than ethanol, better than 95RON.
https://www.sciencedirect.com/science/article/pii/S0360128516300764
On my travels around the literature, I also noticed that MON is misleading garbage for modern fuels in a turbocharged engine (where knock resistance has a positive correlation with sensitivity which is RON-MON). RON is better but still problematic.